The first tin(II) vanadium(III) phosphate SnVPO5: Crystal structure and magnetic properties
β Scribed by Roman V. Shpanchenko; Alexander S. Mitiaev; Victoria V. Chernaya; Evgeny V. Antipov; Hiroya Sakurai; Eiji Takayama-Muromachi
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 354 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0022-4596
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Crystals of the title compound were obtained from hydrothermal treatments. Hg 4 VO(PO 4 ) 2 crystallizes in orthorhombic symmetry with parameters a β«)2(4831.7Ψβ¬ A > , bβ«)3(4576.61Ψβ¬ A > , cβ«)5(7970.9Ψβ¬ A > , Zβ«,4Ψβ¬ and space group Pnma (No. 62). The crystal structure was determined from single cryst
FeP 3 SiO 11 has been prepared by solid state reaction of Fe(PO 3 ) 3 and SiO 2 at 9003C under vacuum. This compound is isotypic with RuP 3 SiO 11 and the atomic coordinates have been re5ned by the Rietveld method. The unit cell is trigonal, space group R-3c, with a β«Ψβ¬ 8.2896(9) A > , c β«Ψβ¬ 39.054(