The First Tetrathio-Substituted Cyclobutane-1,2,3,4-tetracarbonitrile - A New Highly Substituted Cyclobutane
✍ Scribed by Spannenberg, Anke ;Holdt, Hans-Jürgen ;Teller, Joachim ;Praefcke, Klaus ;Kopf, Jürgen
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 279 KB
- Volume
- 1996
- Category
- Article
- ISSN
- 0947-3440
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✦ Synopsis
Abstract
The first tetrathio‐substituted cyclobutane‐1,2,3,4‐tetracarbonitrile 9 was obtained by an intramolecular photoinduced [2 + 2] cycloaddition reaction of the 14‐membered macrocyclic tetrathioether 7 containing two 1,2‐dicyano‐1,2‐dithioethene units in dichloromethane in 73% yield.
📜 SIMILAR VOLUMES
## Abstract The title compound **4** is generated from the phosphoric amide **5** in tetrahydrofuran with butyllithium. The lithium reagent **4** is stable at room temperature; its reactions with electrophiles furnish the products **6–22**, **26**, **27**, see __Table 1__ and the __Scheme__. A seco
Some polyimide films based on cyclobutane-1,2,3,4-tetracarboxylic dianhydride (CBDA) and aromatic diamines were synthesized to investigate their temperature resistance and percent transmission of light. The preparations of CBDA were investigated; they produced almost 10 times the yield of CBDA in co