## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The first synthesis of kaitocephalin based on the structure revision
β Scribed by Hidenori Watanabe; Masayuki Okue; Hiroyuki Kobayashi; Takeshi Kitahara
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 70 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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A stereoselective total synthesis of the proposed structure of kaitocephalin (1) was accomplished starting from L-proline and D-and L-serines. However, its 1 H NMR spectral data and retention time on HPLC were not identical with those of authentic natural kaitocephalin. The revised stereochemistry o
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract The total synthesis of the two isomeric macrocyclic enamides **2** and **17** is described. The precursor **14** was synthesized by means of templateβassisted macrocyclization (__Schemeβ 2__). Isomerization of **14** in the presence of [Fe(CO)~5~] gave **2** and **17** (__Schemeβ 4__). St