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The first synthesis of 16+15-membered bicyclic polypeptide model of A-O-C-B-O-D rings of kistamicin
✍ Scribed by René Beugelmans; Eduardo González Zamora; Georges Roussi
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 199 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
A 16+15 membered bicyclic polypeptide containing biaryl ether bonds, model of A-O-C-B-O-D rings of kistamicin has been synthesized by sequential intramolecular SNAr reactions.
📜 SIMILAR VOLUMES
Synthesis of a 22-membered macrocycle with an endo aryl-aryl ether linkage and a biaryl bond related to the AB-C-O-D ring of vancomycin is described.
The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê