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The First Sodium Uranyl Chromate, Na4[(UO2)(CrO4)3]: Synthesis and Crystal Structure Determination.

✍ Scribed by Sergey V. Krivovichev; Peter C. Burns


Publisher
John Wiley and Sons
Year
2004
Weight
74 KB
Volume
35
Category
Article
ISSN
0931-7597

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Simple Preparations of the Anhydrous and
✍ JeanΒ Claude Berthet; Monique Lance; Martine Nierlich; Michel Ephritikhine πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 297 KB

Treatment of UO 3 with pure triflic acid TfOH at 110 Β°C or with boiling triflic anhydride TfOTf afforded [UO 2 (OTf) 2 ] (1) in high yields. The latter was also prepared by the reaction of UO 3 with TfOH in water, or by dehydration of [UO 2 (OTf) 2 (H 2 O) n ] in boiling TfOTf. Anhydrous [Ce(OTf) 4