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The first oxalate-based 2D coordination polymer containing the biomimetic ligand 5-methyl-1,2,4-triazolo[1,5-a]pyrimidin-7-one

✍ Scribed by Ana B. Caballero; Óscar Castillo; Luis Lezama; Antonio Rodríguez-Diéguez; Juan M. Salas


Book ID
113662058
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
420 KB
Volume
19
Category
Article
ISSN
1387-7003

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1,2-Methyl shift in the reaction of 4,7-
✍ Sergey A. Komykhov; Sergey M. Desenko; Alexander S. Kaganovsky; Valery D. Orlov; 📂 Article 📅 2000 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 115 KB

## Abstract The reaction of the heterocyclic enamine **1** with tosyl azide (**2**) leads to the tosylimino derivative **4** of 1,2,4‐triazolo[1,5‐a]pyrimidine. The extrusion of nitrogen from the primary adduct **3** is followed by a 1,2‐shift of a methyl group. The structure determination of **4**