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The First Organobismuth Rings: (RBi)3 and (RBi)4, R=(Me3Si)2CH

✍ Scribed by Hans Joachim Breunig; Roland Rösler; Enno Lork


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
100 KB
Volume
37
Category
Article
ISSN
0044-8249

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The compounds [(Me 3 SiO) 8 Te 2 O 2 ] (1) and [(Me 4 Si 2 O 2 ) 3 Te] (2) have been prepared in good yields through Bronsted acid-base reaction of Te(OH) 6 with Me 3 SiNEt 2 and Me 4 Si 2 (NEt 2 ) 2 , respectively. They have been characterised by multinuclear NMR spectroscopy and single crystal X-r