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The first molecular superconductor based on the π-acceptor molecule and the closed shell cation, [(CH3)4N][Ni(dmit)2]2

✍ Scribed by Kobayashi, A; Kim, H; Sasaki, Y; Moriyama, S; Nishio, Y; Kajita, K; Sasaki, W; Kato, R; Kobayashi, H

Book ID
122487945
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
353 KB
Volume
27
Category
Article
ISSN
0379-6779

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The synthesis, X-ray structure, magnetic and transport properties of the compound Ni(dmf) 6 [Ni(dsit) 2 ] 2 (dmf=dimethylformamide, dsit=1,3-dithiole-2-thione-4,5-diselenolate) are described. This compound crystallizes in the monoclinic space group P2 1 =c; with a=18.709(6), b=22.975(5), c=20.418(5)