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The First Metal Complexes of the Proton Sponge 1,8-Bis(N,N,N′,N′-tetramethylguanidino)naphthalene: Syntheses and Properties

✍ Scribed by Ute Wild; Olaf Hübner; Astrid Maronna; Markus Enders; Elisabeth Kaifer; Hubert Wadepohl; Hans-Jörg Himmel


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
451 KB
Volume
2008
Category
Article
ISSN
1434-1948

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✍ Markus Albrecht; Klaus Hübler; Wolfgang Kaim 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 127 KB 👁 2 views

The complexes [Ag(g 2 -N 6 S) 2 ](PF 6 ), N 6 S = 1methyl-2-(methylthiomethyl)-1H-benzimidazole, mmb (complex 1) or 1-methyl-2-(tert-butylthiomethyl)-1H-benzimidazole, mtb (complex 2), and [Ag(l,g 2 -mmb)(l,g 2 -O 2 PF 2 )] (complex 3) were synthesized and characterized by X-ray crystallography. Lon