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The first matrix-isolation and electronic structure of vinyl-substituted silylenes

โœ Scribed by Mitsuo Kira; Toyotaro Maruyama; Hideki Sakurai

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
258 KB
Volume
33
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Matrix-isolation and electronic structur
Matrix-isolation and electronic structure of vinyl-substituted silylenes and their complexes with bases [1]
โœ Mitsuo Kira; Toyotaro Maruyama; Hideki Sakurai ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 827 KB

Vinyl-substituted silylenes, 2,5-bis(methylene)-l -silacyclopentane-l ,l -diyl (1) and 2-methybne-1 -silacyclopentane-1 ,I -diyl (2), generated photochemically from the corresponding trisilanes in 3-methylpentane (3-MP) at 77 K, showed broad bands at 505 and 475 nm, respectively, which were assigned