mnizatlon b.md of ethyl radical bns been okcrvcd HI 3 photoelectron spectrometer. i'hc adlabdtic and ~rtic,d P's are 8.30 t: 0.02 eV and 8.55 + 0.02 cV, respcctivcly, and tbc beat ot formatIon of CzltIf is calculated to be 217.1 + "r-1 bcal/mol. Our data arc m good agreement with prcv~ou~ results.
The first ionization potential of the methyl radical as determined by photoelectron spectroscopy
β Scribed by L. Golob; N. Jonathan; A. Morris; M. Okuda; K.J. Ross
- Book ID
- 111712159
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 218 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0368-2048
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π SIMILAR VOLUMES
The ionization potentials of CF4 have been determined by photoelectron spectroscopy. and comparison made xlth the values obtained by an INDO-MO calculation. The theoretical calculations are also used to identify the various ionization processes observed experimentally.
## Abstract The rate constant for the reaction has been determined by means of vacuum ultraviolet flash photolysis and timeβresolved kinetic spectroscopic observations of the 1504βΓ absorption band of CH~3~. The measurements made using three different sources of methyl radicals (azomethane, dimet