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The first intermolecular 2+2 photocycloadditions of 2,5-cyclohexadien-1-ones to alkenes

โœ Scribed by Arthur G Schultz; Arthur G Taveras

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
197 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The type A photorearrangement of 2,5-cyclohexadien-l-ones to bicycloC3.l.Olhex-3-en-2-ones normally occurs with high quantum efficiency. However, we have recently reported1 the first examples of the intramolecular 2+2 photocycloaddition of 4-(3'-alkenyl)-and 4-(3'-pentynyl)-

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