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The First Heterohexametallic Transition-Metal Complex

✍ Scribed by Rico Packheiser; Heinrich Lang


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
88 KB
Volume
2007
Category
Article
ISSN
1434-1948

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## Abstract Lithiated 4‐methyl‐2‐[(trimethylsilyl)amino]pyridine (Ap^TMS^H) undergoes a salt metathesis reaction with [ScCl~3~(thf)~3~] and FeCl~3~, at low temperature in thf, to yield the homoleptic complexes [Sc(Ap^TMS^)~3~] (1) and [Fe(Ap^TMS^)~3~] (2). An analogous reaction with MnCl~2~, CoCl~2