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The First Example of Transition-Metal-Catalyzed Thioformylation of Acetylenes with Aromatic Thiols and Carbon Monoxide

โœ Scribed by Ogawa, Akiya; Takeba, Mitsuo; Kawakami, Jun-ichi; Ryu, Ilhyong; Kambe, Nobuaki; Sonoda, Noboru


Book ID
120881156
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
218 KB
Volume
117
Category
Article
ISSN
0002-7863

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Rhodium-catalyzed highly selective thiof
โœ Jun-ichi Kawakami; Mitsuhiro Takeba; Ikuyo Kamiya; Noboru Sonoda; Akiya Ogawa ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

Highly regioselective thioformylation of terminal acetylenes with thiols and carbon monoxide has been developed by the use of rhodium(I) complexes as the catalyst: formyl and thio groups are introduced into the terminal and inner positions of acetylenes, respectively. The thioformylation is performe