✦ LIBER ✦
The First Example of a True “Turnbull’s Blue” Family Compound with Trapped Iron Oxidation States
✍ Scribed by Vitaly V. Pavlishchuk; Iryna A. Koval; Eugeny Goreshnik; Anthony W. Addison; Gerard A. van Albada; Jan Reedijk
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 345 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
The first compound of a true TurnbullЈs Blue family [i.e. an iron(II) hexacyanoferrate(III)] complex with valence-trapped states of iron
Ukrainian Red, UR) was synthesized. It crystallizes in the trigonal space group P3, a = 12.038(8) A ˚, b = 12.038(8) A ˚, c = 14.342(7) A ˚, α = 90.00°, β = 90.00°, γ = 120.00°. The unit cell of UR consists of separate [Fe([9]ane-S 3 ) 2 ] 2+ cations, [Fe(CN) 6 ] 3-anions and 5.3 molecules of water. Encapsulation of the Fe II in the homo-
[ a] L. V.