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The first enzymatic Achmatowicz reaction: selective laccase-catalyzed synthesis of 6-hydroxy-(2H)-pyran-3(6H)-ones and (2H)-pyran-2,5(6H)-diones

✍ Scribed by Asta, Chimène; Schmidt, Dietmar; Conrad, Jürgen; Förster-Fromme, Bernhard; Tolasch, Till; Beifuss, Uwe


Book ID
121213738
Publisher
The Royal Society of Chemistry
Year
2013
Tongue
English
Weight
421 KB
Volume
3
Category
Article
ISSN
2046-2069

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✍ Ljubov Groesch; Jürgen Kopf; Paul Margaretha 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 German ⚖ 165 KB 👁 1 views

## Abstract The structures of the main products resulting from photocyclodimerization of the title compound **2** and of other 3‐methyl‐substituted ‘oxacyclohex‐2‐en‐1‐ones’ (=dihydropyranones) were determined by X‐ray crystallography. In connection, the ^13^C‐NMR chemical shifts of the cyclobutane