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The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: revision of the absolute stereochemistry of thapsanes

โœ Scribed by A Srikrishna; K Anebouselvy


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
84 KB
Volume
43
Category
Article
ISSN
0040-4039

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First enantioselective synthesis of (+)-
โœ Naoki Toyooka; Hideo Nemoto ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 205 KB

First enantioselective synthesis of quinolizidine 207I has been achieved and the absolute stereochemistry of natural quinolizidine 207I was determined to be 1S,4S,10S by the present chiral synthesis using GC analysis with b-dextrin chiral column on co-injection with racemate.