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The first enantioselective synthesis of both Diels-Alder enantiomers with the same bis(oxazoline)-magnesium perchlorate chiral catalyst

✍ Scribed by Giovanni Desimoni; Giuseppe Faita; Pier Paolo Righetti


Book ID
103403404
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
205 KB
Volume
37
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Can a chiral catalyst containing the sam
✍ Giovanni Desimoni; Giuseppe Faita; Anna Gamba Invernizzi; Pierpaolo Righetti πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 845 KB

The Diels-Alder (DA) reaction between cyclopentadiene (1) and 3-acryloyl-1,3-oxazolidin-2one (2), to give the endo adduet 5 as the main product, has been found to occur enantiosectively in the presence of catalytic amounts of magnesium perchlorate (MP) and 2,2-bis{2-[(4R)-phenyl-, [(4R,5S)and [(4R,5