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The First Enantioselective Intramolecular Aminocarbonylation of Alkenes Promoted by Pd(II)-Spiro Bis(isoxazoline) Catalyst.

โœ Scribed by Toshio Shinohara; Midori A. Arai; Kazuhiko Wakita; Takayoshi Arai; Hiroaki Sasai

Book ID
101941564
Publisher
John Wiley and Sons
Year
2003
Weight
175 KB
Volume
34
Category
Article
ISSN
0931-7597

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The first enantioselective intramolecula
The first enantioselective intramolecular aminocarbonylation of alkenes promoted by Pd(II)-spiro bis(isoxazoline) catalyst
โœ Toshio Shinohara; Midori A. Arai; Kazuhiko Wakita; Takayoshi Arai; Hiroaki Sasai ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 116 KB

The highly ligand acceleration effect of spiro bis(isoxazoline) ligand (SPRIX) on the Pd(II)-catalyzed intramolecular aminocarbonylation of alkenyl amine derivatives was realized. Furthermore, the chiral Pd(II)-SPRIX catalyst accomplished the first enantioselective intramolecular aminocarbonylation.