✦ LIBER ✦
The First Electron-Donor-Acceptor Paracyclophanes with Ferrocene NLO-Phores: Synthesis, Absorption and Electrochemical Properties
✍ Scribed by Kay, Kwang-Yol ;Baek, Yong Gu
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 446 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2940
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✦ Synopsis
Abstract
As potential nonlinear optical material. 12‐nitro‐4,7‐bis(2‐ferrocenylvinyl)[2.2]paracyclophane (1) and 12‐nitro‐4,5,7,8‐tetrakis(2‐ferrocenylvinyl)[2.2]paracyclophane(2) have been synthesized by pd‐catalyzed coupling reactions of vinylferrocene with the precursor cyclophanes 9 and 13, respectively. The absorption and electrochemical properties of 1 and 2 are also described.