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The first benzodiazepine o-quinodimethane: generation and Diels–Alder reactions

✍ Scribed by Minothora Pozarentzi; Julia Stephanidou-Stephanatou; Constantinos A. Tsoleridis

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 131 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(03)00233-8

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✦ Synopsis

7,8-Bis(dibromomethyl)-3-bromo-2,4-diphenyl-3H-benzodiazepine 1 was used as a precursor for the benzodiazepine o-quinodimethane 2, which was trapped by in situ reactions with dienophiles.

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