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The first barbiturate-bridged manganese(II) polymer: Synthesis, crystal structure, and magnetic properties

✍ Scribed by J. Chu; Z. Y. Liu; X. J. Zhao; E. C. Yang

Book ID
111458556
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
410 KB
Volume
36
Category
Article
ISSN
1070-3284

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## Abstract Reactions of Mn(ClO~4~)~2~Β·6H~2~O with FcCO~2~Na [Fc = (Ξ·^5^‐C~5~H~4~)Fe(Ξ·^5^‐C~5~H~5~)] in methanol solution gave [Mn~3~(FcCO~2~)~6~(CH~3~OH)~4~]__~n~__ (1), and, in the presence of 4,4′‐bipyridine (4,4′‐bpy), [Mn~3~(FcCO~2~)~6~(H~2~O)~2~(4,4′‐bpy)]__~n~__ (2). Both complexes have the