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The First Acetimine Gold(I) and Gold(III) Complexes and the First Acetonine Complexes

✍ Scribed by José Vicente; M. Teresa Chicote; Rita Guerrero; Isabel M. Saura-Llamas; Peter G. Jones; M. Carmen Ramírez de Arellano


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
192 KB
Volume
7
Category
Article
ISSN
0947-6539

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Reaction of the cationic binuclear gold(I) complex [(Ph 3 PAu) 2 Cl]BF 4 with w-alkynylfurans furnished phenols as the major product and anellated furans as the side-products. The analogous trimesitylphosphane complex [(Mes 3 PAu) 2 Cl]BF 4 selectively afforded only the phenols. The latter catalyst