A new model is presented for nuclear-spin relaxation in paraspin relaxation was assumed to be due to distortional modumagnetic transition metal complexes in solution, allowing the eleclation of the zero-field splitting (ZFS) interaction. They also tron-spin relaxation to be outside the Redfield limi
The field dependence of 13C relaxation for the cyanide ion in aqueous solution
β Scribed by Roderick E Wasylishen; Werner Danchura; Kirk Marat
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 259 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-2364
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in order to justif\_v tile nrxthemztical postulate of 3 distribution of correI~tion &es, the concept of time-dependen; COTrehtion times is introduced\_ The time dependence arises beause molecules may chmae slope during nuclear relxution\_ The model m3y be used to explain qualit&vely tire fieId depen
The longitudinal proton magnetic relaxation times TI were measured for ferri (met)and carbonmonoxy-bovine haemoglobin and equine myoglobin in 0.1 M KH2P04 aqueous solutions near pH 6 a t 5Β°C and 35Β°C from 1.5-to 60-MHx Larmor frequencies. I t is concluded that the correlation time T C for the dipole