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The facile syntheses of aldehydes and aldehydic acids from carboxylic acid anhydrides using disodium tetracarbonylferrate

✍ Scribed by Yoshihisa Watanabe; Masakazu Yamashita; Take-aki Mitsudo; Masato Tanaka; Yoshinobu Takegami


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
97 KB
Volume
14
Category
Article
ISSN
0040-4039

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A new direct synthesis of cinnamic acids
✍ Constantin I Chiriac; Fulga Tanasa; Marioara Onciu πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 132 KB

Cinnamic acids have been prepared in 59-86% yields by a new direct synthesis from aromatic aldehydes and aliphatic carboxylic acids in the presence of sodium borohydride and N-methyl-2-pyrrolidinone (NMP) as solvent, at reflux (185-190Β°C), for 9-12 hours. Without sodium borohydride, this reaction is