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The Facile Isomerization of 4-Methylene-2-oxazolidinones to 4-Methyl-4-oxazolin-2-ones

✍ Scribed by Stoffel, P. J.; Dixon, W. D.


Book ID
126088561
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
238 KB
Volume
29
Category
Article
ISSN
0022-3263

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AbstractÐN-Substituted 4-methylene-2-isoxazolidinones 9a±9e have been prepared from the tandem condensation of isocyanates 3 with a-ketol 7. In a more polar solvent (DMF) the same reaction led to stereoisomeric alcohols 11 and 12, which could be transformed to the thermodynamically more stable isome