The evaporation of two-component liquid mixtures
β Scribed by J.F. Richardson
- Publisher
- Elsevier Science
- Year
- 1959
- Tongue
- English
- Weight
- 825 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
The ~ffu~~ties of acetone, carbon tetraehloride and water vapours in air have been determined experimentally using the method first developed by WINKELMANN and values have been obtained over a range of operating conditions to an accuracy of within f 2 per cent. The evaporation of two-component liquid mixtures, consisting of a volatile and a non-volatile material has also been been studied in the same apparatus. It has been shown that, when the non-vo~t~e liquid is the denser, the liquid remains completely mixed and the evaporation rate can therefore be simply calculated for rm ideal mixture.
When the non-volatile component is the less dense, convective mixing is negligible and the mass transfer in the liquid is a process of unsteady state molecular diffusion.
π SIMILAR VOLUMES
An associated soIut~on theory based on the UNIQUAC equation IS developed to descnbe the excess propeties of the alcohols m unassociated active components The theory mcludes two association constants the one for the alcohots, the other for alcohol-unassociated active component complexes The theory re