The Ethylene Hot Band Spectrum near 3000 cm−1
✍ Scribed by Jos Oomens; Jörg Reuss; Georg Ch. Mellau; Stefan Klee; Iwona Gulaczyk; André Fayt
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 547 KB
- Volume
- 180
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
✦ Synopsis
A new hot band spectrum of ethylene has been recorded from 2970 to 3015 cm 01 at low rotational temperatures in a seeded molecular jet, using vibrational energy transfer from SF 6 to C 2 H 4 . An IR-IR double resonance technique has been applied to pump the lower states and subsequently probe the hot bands. Two new hot bands, n 10 / n 11 0 n 10 and n 7 / n 11 0 n 7 , have been found. The weak hot band starting from n 7 has been identified by direct labeling of some rotational levels in the n 7 manifold. High resolution FTIR spectra at ambient and at elevated temperatures have been recorded, too; it has thus become possible to extend the analysis to higher rotational quantum numbers. The previously analyzed n 9 / n 10 level has been reinvestigated and a b-type Coriolis interaction with the nearby n 7 / n 11 state has been observed. Rotational energy levels of n 7 / n 11 and of n 9 / n 10 have been fitted simultaneously, taking into account the local perturbations due to five dark states. From the shift of all K x 0 levels to higher frequencies in the n 10 / n 11 state, a global a-type Coriolis interaction with n 8 / 2n 12 has been identified.
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The near-infrared spectra (3000-10 000 cm -1 ) of 4-chlorophenol-OH and 4-chlorophenol-OD are studied at room temperature in carbon tetrachloride. Some data are also reported for 4-bromophenol-OH and 4-bromophenol-OD. The observed absorptions are assigned to overtones or combinations involving the f