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The ESR spectrum and structure of a heteronuclear trimeric cluster, Au2Ag, prepared using a rotating cryostat

โœ Scribed by B. Mile; P.D. Sillman; L. Stokes; A.R. Yacob


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
447 KB
Volume
250
Category
Article
ISSN
0009-2614

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The ESR spectrum and structure of the mi
โœ B. Mile; C.C. Rowlands; P.D. Sillman; A.R. Yacob ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 459 KB

The ESR spectrum of the mixed alkali metal cluster, Na,K,, in an adamantane matrix prepared using a rotating cryostat has been observed. Its isotropic ESR parameters are g = 1.996, u(2Na) = 12.9 mT and &K) = 0.035 mT, indicating a SOMO with most of the unpaired spin density (82%) in the 3s orbitals