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The ESR determination of protein α-helicity

✍ Scribed by K. M. Lvov; Yu. A. Kim


Publisher
Wiley (John Wiley & Sons)
Year
1975
Tongue
English
Weight
467 KB
Volume
14
Category
Article
ISSN
0006-3525

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✦ Synopsis


Abstract

Experimental data are summarized on decay kinetics of uv‐induced paramagnetic centers in globular proteins. The PC decay rate in the absence of oxygen in α helical regions is shown to differ always by about two orders from that in nonhelical regions of the polypeptide chain. This effect can be utilized to estimate the degree of α helicity in the dry state, in solution, and in the frozen solution of proteins.


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