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The EPR spectrum of Os(CO)5+ trapped in a single crystal of Cr(CO)6∗

✍ Scribed by T Lionel; J.R Morton; K.F Preston

Publisher
Elsevier Science
Year
1982
Weight
457 KB
Volume
49
Category
Article
ISSN
0022-2364

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EPR spectrum of the ion pair [CR(CO)5−]2
EPR spectrum of the ion pair [CR(CO)5−]2 in irradiated crystals of PPh4+ HCr(CO)5−
✍ J. R. Morton; K. F. Preston; M. Y. Darensbourg 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 502 KB

UV-irradiated crystals of PPh,+HCr(CO),-exhibit anisotropic EPR spectra at room temperature and below which are characteristic of the presence of an electronic triplet (S = 1). From measurements of the angular dependence of the spectrum it is established that the carrier has axial symmetry with g,,