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The EPR spectrum of O− on magnesium oxide

✍ Scribed by W.B. Williamson; J.H. Lunsford; C. Naccache


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
173 KB
Volume
9
Category
Article
ISSN
0009-2614

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✦ Synopsis


The EPR spectrum of O-on R&O has been observed followin, 0 the reaction of X20 with etectrons trapped at the surface. The spectrum of the ion in axial symmetry is characterized bpg, = 2.04L and g,, = 2.0016. Upon exposure to Hp. CO, CO2 or additional N20 the spectrum is replaced by another having gl = 2.0172, g2 = 2.0100 and g3 = 2.0011. This spectrum is tentatively assigned to the 0, ion.


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The high-resolution infrared spectrum of magnesium oxide 1s reported. The oxide was produced by a low-pressure dischargeenhanced reaction between hot magnesium vapor and nitrous oxide. Fifteen rovlbrational transitions of the fundamental band and seven transitions of the first hot band of MgO (X 'Z-