The enzyme/coenzyme/metal/substrate quaternary complex generated in the transition state of the reduction of benzoylformate with NAD(P)H models

Transition Metal Complexes Coordinated b

Transition Metal Complexes Coordinated by an NAD(P)H Model Compound and their Enhanced Hydride-Donating Abilities in the Presence of a Base

✍ Atsuo Kobayashi; Hideo Konno; Kazuhiko Sakamoto; Akiko Sekine; Yuji Ohashi; Masa 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 367 KB 👁 2 views

## Abstract The ruthenium(II) and rhenium(I) complexes containing an NAD(P)H model compound, 1‐benzyl‐1,4‐dihydronicotinamide (BNAH), as ligand, [Ru(tpy)(bpy)(BNAH)]^2+^ (1 a) and [Re(bpy)(CO)~3~(BNAH)]^+^ (1 b), were quantitatively produced by the reaction of the corresponding metal hydrido comple