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The enthalpy of formation of the C6 molecule from mass spectrometric equilibrium measurements

✍ Scribed by Karl A. Gingerich; Heidi C. Finkbeiner; Richard W. Schmude Jr.

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
372 KB
Volume
207
Category
Article
ISSN
0009-2614

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✦ Synopsis

The equilibrium between graphite and C,(g) has been investigated by Knudsen effusion mass spectrametry at temperatures between 2630 and 2810 K. Together with thermal functions calculated from experimental and theoretical molecular parameters for the linear cumulenic structure, the third law enthalpy of formation, AHr,,= I3 12 + 18 kJ mol-' and the atomization energy AJ&c=2955? 20 kJ mol-', have been obtained.

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