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The Enol Acetylation of 3-Oxo 5β-Steroids

✍ Scribed by Liston, A. J.


Book ID
126301756
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
741 KB
Volume
31
Category
Article
ISSN
0022-3263

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Anomalous enolization of 3-keto-5α-stero
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IT is generally admitted that the greater stability of A2 -over A3-5asteroidal enes determines the A2 structure of 3-keto-Z-steroid enol derivatives.ly2 This structure was actually proved for cholestanone ethyl enol ether, 3 prepared by both pyrolysis of diethylaceta14 and partial hydrogenation of c