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The energy of peroxide bonds in peroxy substituted silanes and the enthalpy of formation of siloxy radicals. The influence of the nature of substituents on the energy of peroxide bonds

✍ Scribed by V. N. Dibrivnyi; Yu. Ya. Van-Chin-Syan; Yu. A. Raevskii


Book ID
110184963
Publisher
International Academic Publishing Co (Nauka/Interperiodica)
Year
2010
Tongue
English
Weight
161 KB
Volume
84
Category
Article
ISSN
0036-0244

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Reactions of Alkyl Radicals with Substit
✍ Abdelfattahβ€…M. Arafat; Samuelβ€…K. Mathew; Solademiβ€…O. Akintobi; Andreasβ€…A. Zavits πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 German βš– 141 KB πŸ‘ 1 views

## Abstract Reactions of isopropyl and of undecyl radicals with __meta‐__ and __para__‐substituted toluenes are reported. The results demonstrate that the reactivities of toluenes are due to both benzyl‐H abstraction and addition of the alkyl radicals to the aromatic ring. Relative reactivities yie