The Energetics of Valence Isomerization in the Norbornadiene−Quadricyclane System
✍ Scribed by Bach, Robert D.; Schilke, Iliana L.; Schlegel, H. Bernhard
- Book ID
- 127104352
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 158 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
## Abstract The previously discussed principles involved in electrocyclic reactions of openshell ions are exemplified for a type C system, the radical cation couple quadricyclane^+^ (**Q**^+^)/norbornadiene^+^ (**NBD**^+^). Exhaustive calculations (MINDO/3) for the various states of the ions suppor
NW palladium complexes of cyclopropenylidenes of the type of trans-ClIPd(CPl(Py-Xl have been synthesized, where CP is di-t-butylcyclopropenyiidene or bis~dlisopropylamino)cyclopropenylidene, and Py-X is I-substrtuted pyridines (X -H, CH3, CNl. The complexes revealed high catalytic activity tovard th