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The energetics of phase transitions in the system Na1+XZr2SiXP3-XO12, 1.9 ⩽ X ⩽ 2.5

✍ Scribed by Thomas Feist; Peter K. Davies; Eva Vogel

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
311 KB
Volume
106
Category
Article
ISSN
0040-6031

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✍ C. Jäger; S. Barth; A. Feltz 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 264 KB

The solid solution Na,+ar,(P0,),\_,( ),has been investigated by \*)Na NMR. The parameters of the quadrupole tensor of the Na( 1) positions in NaZr2(P04), are yq= 1.2kO.l MHz and ~=0.04+0.04. Those for the Na( 1) and Na(2) sites in Na,Zr,(SiO,), are found to be Na( 1): vq= 1.04+0.1 MHz, ~=0.84?0.7; N