✦ LIBER ✦

The elimination of carbon monoxide from acid chlorides. A new method for chloromethyl ether formation.

✍ Scribed by M.H. Palmer; G.J. McVie

Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 168 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)70186-9

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✦ Synopsis

WHEN a-substituted acyl halides are subjected to Friedelcrarte acylatlon conditions , the loss or carbon monoxide la frequently observed (1); thus acylation may be accompanied by or replaced by alkylatlon or olefin formation (2). These reaction8 have been rationalised In terms of unlmolecular decomposition of the acylium complex to a carbonlum ion complex and carbon monoxide, from which the final products are

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