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β¦ LIBER β¦
The electrosynthesis of diaryliodonium salts
β Scribed by Martin J. Peacock; Derek Pletcher
- Book ID
- 104211169
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- French
- Weight
- 55 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
A simple, one-step procedure for the synthesis of diaryliodonium salts is described. It is shown that the electrochemical oxidation of an aryl iodide at a carbon felt anode in acetic acid/25% acetic anhydride/5% sulfuric acid in the presence of an arene leads to a diaryliodonium salt in good yield. The method allows the preparation of unsymmetrical, as well as symmetrical diaryliodonium salts.
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