The electroreduction of fluoropentamminocobalt(III) cation in the presence of specifically adsorbed nitrate anions
โ Scribed by W. Ronald Fawcett; Peter H. Solomon
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 645 KB
- Volume
- 251
- Category
- Article
- ISSN
- 0022-0728
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๐ SIMILAR VOLUMES
In a systematic study of the effect of specific ionic adsorption upon the kinetics of electrode processes carried out in this laboratory ~-3 we found it interesting to examine the influence of halide and pseudohalide adsorption upon the reduction rate of BrO4 ion. The polarographic behaviour of BrO2
4+ accelerates the electroreduction of NO -3 in sulfuric acid solutions in the potential region close to a complete coverage of the surface by H ads in the supporting electrolyte. The electrocatalytic effect increases from Ge via Ni to Co โ Cd. Ge adatoms promote the NO -3 electroreduction most eff