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The electrophilically initiated ring opening of some cyclobutanone derivatives

✍ Scribed by R.D. Miller; D.R. McKean

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
181 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cyclobutanone derivatives by virtue of their reactivity have proved to be valuable synthetic intermediates, and recent synthetic advances have increased their accessibility.' Most useful transformations of these compounds are initiated by addition of reagents to the strained carbonyl and subsequent ring expansion, contraction or opening. Ring enlargement usually involves bond migration to an election deficient center (e.g., Baeyer-Villiger oxidation) while

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