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The electronic structures of bis(η 6 -benzene)- and bis(η 6 -naphthalene)chromium(0)

✍ Scribed by Weber, Jaques; Kundig, E. Peter; Goursot, Annick; Penigault, Edouard


Book ID
121808775
Publisher
NRC Research Press
Year
1985
Tongue
French
Weight
433 KB
Volume
63
Category
Article
ISSN
0008-4042

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dine 4-oxide (2f): (3.f) (2.9g, 10mmol) is heated to 160 to 170°C for 5 h in a slow current of N2. B(CH3)3 (0.5 g, 90 %) ) condenses in a cold trap at -78°C. Only (2f) can be detected in the residue by NMR spectroscopy. Distillation at 65 "C/0.3 torr afforded (2 f) (1.8 g, 78 %) as a colorless liqui