The Electronic Structure of Vinyl Ethers and Sulfides with Interrupted Conjugation Examined by Photoelectron Spectroscopy

✍ Scribed by Christopher Batich; Edgar Heilbronner; Clayton B. Quinn; John R. Wiseman

• Publisher: John Wiley and Sons
• Year: 1976
• Tongue: German
• Weight: 606 KB
• Volume: 59
• Category: Article
• ISSN: 0018-019X
• DOI: 10.1002/hlca.19760590217

✦ Synopsis

Abstract

Photoelectron spectroscopy has been used to examine the consequences of steric inhibition of conjugation in a distorted vinyl sulfide and vinyl ether. Based upon the degree of interaction a deviation from coplanarity of 70°–75° is calculated for 9‐oxabicyclo[3.3.1]non‐1‐ene (3) and approximately 75°–80° for the sulfur analog 6.