The electronic structure of unstable intermediates. VI. the electronic structure of AICN, AINC, PCN, and PNC and comparison with their 1st-row analogues

Base Hydrolysis of (Acidato)(Pentaamine)

Base Hydrolysis of (Acidato)(Pentaamine) Complexes with Inert Metal Centers: Electronic Structure of the Intermediates, Requirements for Their Formation, and the Unique Reactivity of the Complexes of Cobalt(III)

✍ François P. Rotzinger; Jacques Weber; Claude Daul 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 933 KB

## Abstract Molecular‐orbital calculations have been performed for the conjugate base __cis__‐[Co(NH~3~)~4~(NH~2~)Cl]^+^ and __trans__‐[M(NH~3~)~4~(NH~2~)Cl]^+^ (M = Cr^III^, Co^III^, and Rh^III^), the hexacoordinated intermediates __cis‐__ and __trans__‐[Co(NH~3~)~4~(NH~2~)…Cl]^+^, the square‐pyra