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The electronic structure of the one-dimensional tetrahedrally distorted porphyrinatonickel (II) system

✍ Scribed by Michael C. Böhm


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
451 KB
Volume
102
Category
Article
ISSN
0375-9601

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The effect of distortion and of changes in coordination on the ligand field spectrum of tetrahedral nickel in solution and in single crystals at temperatures down to 10 K is described. Dilution of a solution of NiCI~-produces a change from tetrahedral to five-coordination. The spectrum of the intens