The electronic structure of aryl thiol e
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J.R. Grunwell; S.I. Hanhan
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Article
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1973
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Elsevier Science
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French
β 473 KB
A combination of experimental data and the CNDO/Z-SCF-MO method are used to evaluate the importance of d-orbitals to the electronic structure of aryl thiol esters. The thioester group IS calculated to withdraw electron density through o and 2p,, -3d, bonding and donate by p,, -pm bonding. Electron d