The electronic structure of NiO investigated by photoemission spectroscopy
✍ Scribed by S. Hüfner; P. Steiner; I. Sander; F. Reinert; H. Schmitt; M. Neumann; S. Witzel
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 357 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0038-1098
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The chemistry of binary and multinary silver oxides spans from subvalent species (with a mean oxidation number for Ag smaller than + 1) to compounds with Ag in high oxidation states as + 2 and + 3. We have investigated a range of silver oxides, including the binary compounds Ag 2 O, AgO, Ag 3 O 4 an
The X-ray and W photoemission valence band spectra of NiO are interpreted using the molecular orbital theory for the NiOpcluster and the sudden approsimation (monopole selection rules). They exhibit the effects of crystal field splitting, multiplet splitting, electron shake-up (0 2pe$' -Ni 3dea). re