The electronic spectrum of SiH4: Jahn-Teller Rydberg series
✍ Scribed by Velasco, A. M.; Lavín, C.; Sánchez de Merás, A. M. J.; Sánchez Marín, J.
- Book ID
- 115439950
- Publisher
- American Institute of Physics
- Year
- 2011
- Tongue
- English
- Weight
- 341 KB
- Volume
- 135
- Category
- Article
- ISSN
- 0021-9606
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📜 SIMILAR VOLUMES
We present a theoretical account of the Jahn-Teller (JT) and pseudo-Jahn-Teller (PJT) effects in the photoelectron spectrum of cyclopropane. The PJT interactions between the two JT split X 2 E 0 and Ã2 E 00 electronic states of the cyclopropane radical cation are examined. Nuclear dynamical simulati
## Reparameterized CNDO calculations on the ground and ffrst excited states of the cycfopropaue caD"on sboow that both states are subject to significant J&n-Teller distortions. First and second order vibroaic coupling parameters derived from the calcuIations are used to predict the shape of spectr