The electron paramagnetic resonance and optical spectra of copper and vanadium in phosphate glasses
β Scribed by L.D. Bogomolova; V.A. Jachkin; V.N. Lazukin; T.K. Pavlushkina; V.A. Shmuckler
- Book ID
- 118330695
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 861 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3093
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EPR and optical absorption investigations of chromium doped cadmium phosphate glass are carried out. Crystal field, spin-Hamiltonian and bonding parameters are evaluated. From the results and analyses of the EPR and optical studies, the site symmetry of Cr 3ΓΎ ion in the glass is ascribed to a distor
In this work, a full ligand-field energy matrix diagonalization treatment for 3d 1 ions in tetragonal symmetry is developed on the basis of the two-s.o.-coupling-parameter model, and the contributions of the spin-orbit coupling of the ligand ions to the optical and EPR spectra are included. Spin Ham